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Production of plasticizers can be shortly divided in few steps:
Esterification is an equilibrium chemical reaction which is caried
out as a batch process in the reactor containing an agitator and other
equipment – particularly for water separation and removal which is
formed during chemical reaction.
First phthalic anhydride and the 2-ethyhexanol are mixed in the
reactor in order to form the monoester - mono-2-ethylhexylphtalate. The
reaction takes place at about 150°C. Further the reaction mixture is
heated to 170 - 180°C. At this point the catalyst tetrabutyl-titanate
is added. Before the addition care must be taken to separate all the
water formed in chemical reaction from the system. The evolution of
reaction takes place and water formed must be continously carefully
separated in the alcohol water separator. The temperature in the
reactor is further increased up to 220-235°C to terminate the
esterification. The Raw DOP is obtained.
- Distillation and Neutralization
Raw DOP is transferred to the distillation section which consists
of an reactor equipped with the stirrer, vapors condenser, cooler and
alcohol water separator.
The alcohol is distilled first under mild vacuum distillation and at
the end with vacuum distillation and steam stripping. At about
170-180°C sodium carbonate is introduced to neutralize the traces of
the monoester. The hydrolysis of the tetrabutyltitanate is performed in
next step by adding small amounts of water. After the hydrolysis filter
aid (diatomite earth) is added and DOP is dried under vacuum and a
light flow of nitrogen.
In this phase, solids formed or aded (diatomite earth) during
neutralization and hydrolysis of the catalyst are removed by
filtration.Other types of plasticizers are produced on the same
equipment using different raw materials.
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